Product ID:00375 UNLEADED PLUS
MSDS Date:10/24/1990
FSC:9130
NIIN:01-272-0983
MSDS Number: BPCFG

TEXACO INC.

BEACON, NY 12508-0509
US

Emergency Phone: 914-831-3400/800-424-9300(CHEMTREC)

Info Phone: 914-838-7509

Preparer: M.J. VON ALLMEN

Cage: 38431

TEXACO INC

509 BEACON, NY 12508-0509 US

Telephone: 914-831-3400

Cage: 7B131

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-3.99%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 4-10.99%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-3.99%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4-10.99%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-3.99%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15% V%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

GASOLINE (ABOVE LISTED INGREDIENTS CONTAINED IN GASOLINE)

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 95-100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

ALIPHATIC PETROLEUM SOLVENT

CAS: 8008-20-6

RTECS: OA5500000

Fraction By Weight: .01-.09%

OSHA PEL 400 PPM PETR. DIST.

ACGIH TLV: 400 PPM RUBBER SOLV.

LD50 LC50 Mixture:ORAL LD50 (RAT) = 18.75 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: CONTACT MAY CAUSE EYES AND SKIN
IRRITATION. INHALATION AND INGESTION MAY CAUSE IRRITATION AND
CENTRAL NERVOUS SYSTEM EFFECTS. ASPIRATION MAY CAUSE LUNG DAMAGE.
CHRONIC: RECENT STUDIES WITH LABO RATORY ANIMALS HAVE SHOWN THAT
GASOLINEVAPORS CAUSE KIDNEY DAMAGE AND KIDNEY CANCER IN RATS AND
LIVER CANCER IN MICE.
Explanation of Carcinogenicity:PRODUCT CONTAINS BENZENE WHICH IS LISTED
AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:RESPIRATORY SYSTEM: MAY CAUSE DIZZINESS,
IRRITATION OF EYES, NOSE AND THROAT, VOMITING, BLUISH COLOR OF THE
SKIN AND CENTRAL NERVOUS SYSTEM EFFECTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES. SKIN: WASH EXPOSED
AREA WITH SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING. MAY
CAUSE CHEMICAL PNEUMONITIS. CALL A PHYSICIAN. INHALATION: SHOULD
SYMPTOMS NOT ED UNDER EXPOSURE OCCUR, REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. (REMOVE GASOLINE-SOAKED
CLOTHING)

Flash Point Method:COC
Flash Point:-40F,-40C
Autoignition Temp:Autoignition Temp Text:850F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE. DO NOT USE
DIRECT WATER STREAM.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD
BE USED TO COOL FIRE-EXPOSED CONTAINERS. IF A SPILL OR LEAK HAS NOT
IGNITED, USE WATER SPRAY TO DISPERSE VAPORS.
Unusual Fire/Explosion Hazard:FLOWING GASOLINE CAN BE IGNITED BY
SELF-GENERATED STATIC ELECTRICITY. USE ADEQUATE GROUNDING. CARBON
MONOXIDE AND CARBON DIOXIDE MAY BE FORMED ON BURNING IN AIR

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES INCLUDING
INTERNAL COMBUSTION ENGINES AND POWER TOOLS. VENTILATE AREA. AVOID
BREATHING VAPORS. USE SCBA OR SUPPLIED-AIR MASK FOR LARGE SPILLS IN
CONFINED AREAS. CONTAIN SPILL IF POSSIBLE. REMOVE WITH INERT
ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:TRANSPORT, HANDLE AND STORE IN
ACCORDANCE WITH OSHA REGULATION 1910.106 AND APPLICABLE D.O.T.
REGULATIONS.
Other Precautions:DANGER! EXTREMELY FLAMMABLE. HARMFUL OR FATAL IF
SWALLOWED. MAY BE FATAL IF INHALED; MAY CAUSE IRRITATION. MAY BE
HARMFUL IF ABSORBED THROUGH THE SKIN. KEEP AWAY FROM HEAT, SPARKS
AMD FLAMES. AVOID BR EATHING VAPORS. FOR USE AS MOTOR FUEL.

Respiratory Protection:SCBA OR SUPPLIED AIR RESPIRATORY PROTECTION
REQUIRED FOR ENTRY INTO TANKS, VESSELS, OR OTHER CONFINED SPACES
CONTAINING GASOLINE.
Ventilation:ADEQUATE TO MEET PERMISSIBLE CONCENTRATIONS.
Protective Gloves:NITRILE, TEFLON, VITON
Eye Protection:CHEMICAL-TYPE GOGGLES, FACE SHIELD
Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS,
COVERALLS OR LAB COATS SHOULD BE WORN.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER OR DRY
CLEAN CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE.

HCC:F2
Boiling Pt:B.P. Text:>90F,>32C
Vapor Density:3 - 4.0
Spec Gravity:0.7 -0.77
Solubility in Water:SLIGHT
Appearance and Odor:LIGHT STRAW TO LIGHT RED LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT, SPARKS, FLAME AND OTHER SOURCES OF
IGNITION.
Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE,
CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES.

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
RCRA WASTE NUMBER D001.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.